An introduction to minerals and rocks under the microscope
An introduction to minerals and rocks under the microscope

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An introduction to minerals and rocks under the microscope

2.2.2 Double refraction

Anisotropic crystals have a remarkable property: when plane-polarised light enters such a crystal, it splits into two rays. The explanation for this involves complex crystal physics, which is well beyond the scope of this course. Nevertheless, the consequences are profound. The two rays are each plane-polarised, but their planes of polarisation (i.e. their vibration directions) are at 90° to each other. This means that each ray encounters a different atomic arrangement and therefore travels at a different speed through the crystal - so they have different refractive indices. The difference in refractive index of the two rays is called birefringence. If the refractive indices are very different (i.e. the crystal has a very high birefringence), then the two rays will be refracted to very different extents, and it may be possible to view two distinct images through the crystal, one for each ray. This effect, called double refraction, can be seen in the transparent variety of calcite, Iceland spar (Figure 29).

Figure 29 (a) Side-view through a calcite cleavage rhomb, showing how light is doubly refracted into two rays as it passes through the crystal. For calcite, the refractive indices (or speeds) of the two rays are very different, so they travel along quite different paths through the crystal. (b) Double refraction in natural calcite (Iceland spar). The difference in the speeds (i.e. refractive indices) of the two rays is so great that the eye perceives two images.
  • Would you expect to see double refraction in a cubic crystal?

  • No. Cubic crystals are isotropic. Double refraction occurs only in anisotropic crystals.

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