2.4 Operators and superposition
In quantum mechanics, an operator is a mathematical entity which converts one function into another function and is written with a ‘hat’on, for example , (pronounced ‘A hat’). Given an operator , the eigenvalue equation for that operator is
Here, is a constant known as an eigenvalue, which may be complex, and is function known as an eigenfunction. There may be more than one eigenvalue and corresponding eigenfunction associated with each eigenvalue equation. The eigenvalue matrix equation, Equation (2) as described in Section 2.2 is an example of this type of equation with the operator written as a matrix and the eigenfunction as a column vector.
Consider an operator with two eigenvectors and two corresponding eigenvalues so that
Since and are both eigenfunctions or solutions of the eigenvalue equation any linear combination of and is also a solution. Such a linear combination, known as a superposition, is
where and are complex numbers.
Exercise 7
The wave function of a free particle in quantum mechanics may be written as
Confirm that is an eigenfunction of (where indicates a partial derivative) and show that the eigenvalue is the energy of the free particle, . ( is the reduced Planck’s constant.)
Answer
Operating on with we find that
Thus the free-particle wave function is an eigenfunction of and the corresponding eigenvalue is the energy, , associated with this wave.